{"id":1353,"date":"2024-07-11T09:41:18","date_gmt":"2024-07-11T09:41:18","guid":{"rendered":"https:\/\/eng.rizvi.edu.in\/humanities\/?p=1353"},"modified":"2024-07-16T10:10:57","modified_gmt":"2024-07-16T10:10:57","slug":"recent-trend-in-chemistry","status":"publish","type":"post","link":"https:\/\/eng.rizvi.edu.in\/humanities\/recent-trend-in-chemistry\/","title":{"rendered":"Recent Trend in Chemistry"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"1353\" class=\"elementor elementor-1353\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-top-section elementor-element elementor-element-7051014 elementor-section-stretched elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"7051014\" data-element_type=\"section\" data-settings=\"{&quot;stretch_section&quot;:&quot;section-stretched&quot;,&quot;background_background&quot;:&quot;classic&quot;}\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-top-column elementor-element elementor-element-1b8ff74\" data-id=\"1b8ff74\" data-element_type=\"column\" data-settings=\"{&quot;background_background&quot;:&quot;classic&quot;}\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-1a1a155 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"1a1a155\" data-element_type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-inner-column elementor-element elementor-element-5f8ac8b\" data-id=\"5f8ac8b\" data-element_type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-e2bbf54 elementor-widget-tablet__width-initial elementor-invisible elementor-widget elementor-widget-heading\" data-id=\"e2bbf54\" data-element_type=\"widget\" data-settings=\"{&quot;_animation&quot;:&quot;pulse&quot;}\" data-widget_type=\"heading.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t<style>\/*! elementor - v3.22.0 - 26-06-2024 *\/\n.elementor-heading-title{padding:0;margin:0;line-height:1}.elementor-widget-heading .elementor-heading-title[class*=elementor-size-]>a{color:inherit;font-size:inherit;line-height:inherit}.elementor-widget-heading .elementor-heading-title.elementor-size-small{font-size:15px}.elementor-widget-heading .elementor-heading-title.elementor-size-medium{font-size:19px}.elementor-widget-heading .elementor-heading-title.elementor-size-large{font-size:29px}.elementor-widget-heading .elementor-heading-title.elementor-size-xl{font-size:39px}.elementor-widget-heading .elementor-heading-title.elementor-size-xxl{font-size:59px}<\/style><h2 class=\"elementor-heading-title elementor-size-default\">Recent Trend in Chemistry\n<\/h2>\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<section class=\"elementor-section elementor-inner-section elementor-element elementor-element-02c6697 elementor-section-boxed elementor-section-height-default elementor-section-height-default\" data-id=\"02c6697\" data-element_type=\"section\">\n\t\t\t\t\t\t<div class=\"elementor-container elementor-column-gap-default\">\n\t\t\t\t\t<div class=\"elementor-column elementor-col-100 elementor-inner-column elementor-element elementor-element-a4eaa28\" data-id=\"a4eaa28\" data-element_type=\"column\">\n\t\t\t<div class=\"elementor-widget-wrap elementor-element-populated\">\n\t\t\t\t\t\t<div class=\"elementor-element elementor-element-8909fa5 elementor-invisible elementor-widget elementor-widget-text-editor\" data-id=\"8909fa5\" data-element_type=\"widget\" data-settings=\"{&quot;_animation&quot;:&quot;fadeIn&quot;}\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t<style>\/*! elementor - v3.22.0 - 26-06-2024 *\/\n.elementor-widget-text-editor.elementor-drop-cap-view-stacked .elementor-drop-cap{background-color:#69727d;color:#fff}.elementor-widget-text-editor.elementor-drop-cap-view-framed .elementor-drop-cap{color:#69727d;border:3px solid;background-color:transparent}.elementor-widget-text-editor:not(.elementor-drop-cap-view-default) .elementor-drop-cap{margin-top:8px}.elementor-widget-text-editor:not(.elementor-drop-cap-view-default) .elementor-drop-cap-letter{width:1em;height:1em}.elementor-widget-text-editor .elementor-drop-cap{float:left;text-align:center;line-height:1;font-size:50px}.elementor-widget-text-editor .elementor-drop-cap-letter{display:inline-block}<\/style>\t\t\t\t<p><b>Vitamin C-induced CO<\/b><b>2<\/b><b>&nbsp;capture enables high-rate ethylene production in CO<\/b><b>2<\/b><b>&nbsp;electroreduction<\/b><\/p>\n<p>2 Jan 2024 Nature Communications (Open access online Journal) 15 Edition article number 192 has<br>published this, it is the work of Jongyoun Kim, Taemin Lee, Minkyoung , Jungsu Eo and others.<\/p>\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-12f51c7 elementor-invisible elementor-widget elementor-widget-text-editor\" data-id=\"12f51c7\" data-element_type=\"widget\" data-settings=\"{&quot;_animation&quot;:&quot;fadeIn&quot;}\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<p><b>As the requirement <\/b><span style=\"font-weight: 400\">of energy and continuous fuel supply is concern, we are still struggling, this article shows the way how to prepare carbon-based fuels with the help of Vitamin C, Cu nano wire, CO2 and electric field.<\/span><\/p><p><span style=\"font-weight: 400\">The electrochemical CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0reduction reaction (CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">RR) to form value-added fuels and feedstocks is a promising route to achieve carbon neutrality and long-term energy storage. The development of CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">RR electrocatalysts has led to advances in selectivity for multicarbon (C<\/span><span style=\"font-weight: 400\">2+<\/span><span style=\"font-weight: 400\">) chemicals such as ethylene (C<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">H<\/span><span style=\"font-weight: 400\">4<\/span><span style=\"font-weight: 400\">)\u00a0and ethanol (C<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">H<\/span><span style=\"font-weight: 400\">5<\/span><span style=\"font-weight: 400\">OH)\u00a0with high energy density and a high market price.\u00a0<\/span><\/p><p><span style=\"font-weight: 400\">Here, we report molecularly enhanced CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">-to-*CO conversion and *CO dimerization for high-rate C<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">H<\/span><span style=\"font-weight: 400\">4<\/span><span style=\"font-weight: 400\">\u00a0production using ascorbic acid (AA). AA, also known as vitamin C, has been widely used as a reducing agent and antioxidant in nanomaterial synthesis and biochemical purposes. When we store fruits to preserve AA, maintaining a CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">-deficient environment is essential because AA can react with CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0and be oxidized to dehydroascorbic acid (DHA) with proton and electron donation. Furthermore, AA has been utilized for CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0capture in homogeneous catalysis approache. Inspired by this AA\/DHA redox principle and CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0capture property, we exploited AA as a promoter to capture CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0near Cu, increase the *CO coverage and ensuing *CO dimerization on the surface of heterogeneous Cu catalysts.<\/span><\/p><p><span style=\"font-weight: 400\">To employ AA in heterogeneous catalysis with aqueous electrolytes, we pursued a strategy to immobilize water-soluble AA on electrocatalysts and achieve redox reversibility. We designed AA-augmented Cu nanowires (CuNWs) by applying graphene quantum dots (GQDs), which contain \u2212OH and \u2212COOH groups, as a mediator to anchor AA on the Cu surface with an ionomer. This nanoconfined AA on CuNW enhanced the CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">-to-*CO conversion during the CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">RR and resulted in high C<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">H<\/span><span style=\"font-weight: 400\">4<\/span><span style=\"font-weight: 400\">\u00a0productivity of heterogeneous Cu electrocatalysts. Unlike pristine CuNW (p-CuNW), which mainly produced C<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">H<\/span><span style=\"font-weight: 400\">4<\/span><span style=\"font-weight: 400\">\u00a0at low potential, CuNW with AA nanoconfined by GQDs (cAA-CuNW) boosted CO production over a similar potential range. As the potential increased for the high-current-density CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">RR, enriched CO formation in cAA-CuNW was dramatically converted to C<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">H<\/span><span style=\"font-weight: 400\">4<\/span><span style=\"font-weight: 400\">, while the main electrolysis product of p-CuNW was hydrogen (H<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">) because of limited CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0mass transport. We found that this enables efficient CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">RR even in low CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0concentrations, which can be extended to the CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">RR of flue gas. In situ Raman spectroscopy and operando X-ray absorption spectroscopy (XAS) studies enabled us to verify the effect of nanoconfined AA for inducing a high degree of *CO coverage and binding control between atop-bound CO (CO<\/span><span style=\"font-weight: 400\">atop<\/span><span style=\"font-weight: 400\">) and bridge-bound CO (CO<\/span><span style=\"font-weight: 400\">bridge<\/span><span style=\"font-weight: 400\">) on the reconstructed CuNW during the CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">RR. Grand canonical density functional theory (GC-DFT) revealed that the redox of AA\/DHA enabled efficient electron\/proton transfer to CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0and multiple hydrogen bonding sites of AA, thereby improving CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">-to-*CO conversion and *CO dimerization on Cu.<\/span><\/p>\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-9628ce1 elementor-widget elementor-widget-image\" data-id=\"9628ce1\" data-element_type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t<style>\/*! elementor - v3.22.0 - 26-06-2024 *\/\n.elementor-widget-image{text-align:center}.elementor-widget-image a{display:inline-block}.elementor-widget-image a img[src$=\".svg\"]{width:48px}.elementor-widget-image img{vertical-align:middle;display:inline-block}<\/style>\t\t\t\t\t\t\t<figure class=\"wp-caption\">\n\t\t\t\t\t\t\t\t\t\t<img fetchpriority=\"high\" decoding=\"async\" width=\"678\" height=\"582\" src=\"https:\/\/eng.rizvi.edu.in\/humanities\/wp-content\/uploads\/sites\/8\/2024\/07\/humanities-1.png\" class=\"attachment-large size-large wp-image-1351\" alt=\"\" srcset=\"https:\/\/eng.rizvi.edu.in\/humanities\/wp-content\/uploads\/sites\/8\/2024\/07\/humanities-1.png 678w, https:\/\/eng.rizvi.edu.in\/humanities\/wp-content\/uploads\/sites\/8\/2024\/07\/humanities-1-300x258.png 300w\" sizes=\"100vw\" \/>\t\t\t\t\t\t\t\t\t\t\t<figcaption class=\"widget-image-caption wp-caption-text\">Fig. 1: CO2 capture strategy and surface structures of AA-augmented CuNWs.<\/figcaption>\n\t\t\t\t\t\t\t\t\t\t<\/figure>\n\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-7708b5e elementor-widget elementor-widget-text-editor\" data-id=\"7708b5e\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t<p><b>a<\/b><span style=\"font-weight: 400\">\u00a0Schematic of enhanced CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">-to-*CO conversion and *CO dimerization in cAA-CuNW for high-rate C<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">H<\/span><span style=\"font-weight: 400\">4<\/span><span style=\"font-weight: 400\">\u00a0production.\u00a0<\/span><b>b<\/b><span style=\"font-weight: 400\">\u00a0Redox of AA and DHA for CO<\/span><span style=\"font-weight: 400\">2<\/span><span style=\"font-weight: 400\">\u00a0capture.\u00a0<\/span><b>c<\/b><span style=\"font-weight: 400\">\u00a0Schematic illustration of surface modification of CuNWs with GQD, AA, and nanoconfined AA on GQDs. An ionomer is coated on the outer surface of CuNWs during the fabrication of the GDE. TEM (top) and HR-TEM (bottom) images of (<\/span><b>d,<\/b><span style=\"font-weight: 400\">\u00a0<\/span><b>e<\/b><span style=\"font-weight: 400\">) p-CuNW, (<\/span><b>f,<\/b><span style=\"font-weight: 400\">\u00a0<\/span><b>g<\/b><span style=\"font-weight: 400\">) G-CuNW, (<\/span><b>h,<\/b><span style=\"font-weight: 400\">\u00a0<\/span><b>i<\/b><span style=\"font-weight: 400\">) AA-CuNW, and (<\/span><b>j,<\/b><span style=\"font-weight: 400\">\u00a0<\/span><b>k<\/b><span style=\"font-weight: 400\">) cAA-CuNW.<\/span><\/p>\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<div class=\"elementor-element elementor-element-3b3f81b elementor-widget elementor-widget-image\" data-id=\"3b3f81b\" data-element_type=\"widget\" data-widget_type=\"image.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t\t<figure class=\"wp-caption\">\n\t\t\t\t\t\t\t\t\t\t<img decoding=\"async\" width=\"481\" height=\"615\" src=\"https:\/\/eng.rizvi.edu.in\/humanities\/wp-content\/uploads\/sites\/8\/2024\/07\/humanities-2.png\" class=\"attachment-large size-large wp-image-1352\" alt=\"\" srcset=\"https:\/\/eng.rizvi.edu.in\/humanities\/wp-content\/uploads\/sites\/8\/2024\/07\/humanities-2.png 481w, https:\/\/eng.rizvi.edu.in\/humanities\/wp-content\/uploads\/sites\/8\/2024\/07\/humanities-2-235x300.png 235w\" sizes=\"100vw\" \/>\t\t\t\t\t\t\t\t\t\t\t<figcaption class=\"widget-image-caption wp-caption-text\">Fig. 5: Computational modeling of the CO2RR on Cu (100) and AA\/Cu (100).\n<\/figcaption>\n\t\t\t\t\t\t\t\t\t\t<\/figure>\n\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t<\/section>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>\/*! elementor &#8211; v3.22.0 &#8211; 26-06-2024 *\/ .elementor-heading-title{padding:0;margin:0;line-height:1}.elementor-widget-heading .elementor-heading-title[class*=elementor-size-]&gt;a{color:inherit;font-size:inherit;line-height:inherit}.elementor-widget-heading .elementor-heading-title.elementor-size-small{font-size:15px}.elementor-widget-heading .elementor-heading-title.elementor-size-medium{font-size:19px}.elementor-widget-heading .elementor-heading-title.elementor-size-large{font-size:29px}.elementor-widget-heading .elementor-heading-title.elementor-size-xl{font-size:39px}.elementor-widget-heading .elementor-heading-title.elementor-size-xxl{font-size:59px} Recent Trend in Chemistry Vitamin C-induced CO2&nbsp;capture enables high-rate ethylene production in CO2&nbsp;electroreduction 2 Jan 2024 Nature Communications (Open access online Journal) 15 Edition article number 192 haspublished this, it is the work of Jongyoun Kim, Taemin Lee, Minkyoung , Jungsu &hellip; <\/p>\n<p class=\"link-more\"><a href=\"https:\/\/eng.rizvi.edu.in\/humanities\/recent-trend-in-chemistry\/\" class=\"more-link\">Read more<span class=\"screen-reader-text\"> &#8220;Recent Trend in Chemistry&#8221;<\/span><\/a><\/p>\n","protected":false},"author":13,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"om_disable_all_campaigns":false,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-1353","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v22.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Recent Trend in Chemistry - Humanities &amp; Sciences<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/eng.rizvi.edu.in\/humanities\/recent-trend-in-chemistry\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Recent Trend in Chemistry - Humanities &amp; Sciences\" \/>\n<meta property=\"og:description\" content=\"\/*! elementor &#8211; v3.22.0 &#8211; 26-06-2024 *\/ .elementor-heading-title{padding:0;margin:0;line-height:1}.elementor-widget-heading .elementor-heading-title[class*=elementor-size-]&gt;a{color:inherit;font-size:inherit;line-height:inherit}.elementor-widget-heading .elementor-heading-title.elementor-size-small{font-size:15px}.elementor-widget-heading .elementor-heading-title.elementor-size-medium{font-size:19px}.elementor-widget-heading .elementor-heading-title.elementor-size-large{font-size:29px}.elementor-widget-heading .elementor-heading-title.elementor-size-xl{font-size:39px}.elementor-widget-heading .elementor-heading-title.elementor-size-xxl{font-size:59px} Recent Trend in Chemistry Vitamin C-induced CO2&nbsp;capture enables high-rate ethylene production in CO2&nbsp;electroreduction 2 Jan 2024 Nature Communications (Open access online Journal) 15 Edition article number 192 haspublished this, it is the work of Jongyoun Kim, Taemin Lee, Minkyoung , Jungsu &hellip; 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Sciences","og_description":"\/*! elementor &#8211; v3.22.0 &#8211; 26-06-2024 *\/ .elementor-heading-title{padding:0;margin:0;line-height:1}.elementor-widget-heading .elementor-heading-title[class*=elementor-size-]&gt;a{color:inherit;font-size:inherit;line-height:inherit}.elementor-widget-heading .elementor-heading-title.elementor-size-small{font-size:15px}.elementor-widget-heading .elementor-heading-title.elementor-size-medium{font-size:19px}.elementor-widget-heading .elementor-heading-title.elementor-size-large{font-size:29px}.elementor-widget-heading .elementor-heading-title.elementor-size-xl{font-size:39px}.elementor-widget-heading .elementor-heading-title.elementor-size-xxl{font-size:59px} Recent Trend in Chemistry Vitamin C-induced CO2&nbsp;capture enables high-rate ethylene production in CO2&nbsp;electroreduction 2 Jan 2024 Nature Communications (Open access online Journal) 15 Edition article number 192 haspublished this, it is the work of Jongyoun Kim, Taemin Lee, Minkyoung , Jungsu &hellip; 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